Hi Timo,
Thank you for the mail.
1. There might be a lot of mail stuck in the mail queue, it will impact the performance.
See below for complete command lines input into DS in console interface(CLI).
1.Please enable the TELNET or SSH function in Web UI of your Synology NAS . ( [Nework Service] > [Terminal] )
2.
Open Window's Command Line or any other telnet clients (such as PuTTY), Mac's Terminal, or Linux's Console, depending on which platform you are using.
Connect to DiskStation with Telnet/SSH:
telnet 192.168.xxx.xxx (DiskStation's IP address)
Log in with the root account and DiskStation admin's password.
http://putty.managedownloads.com/
http://www.synology.com/support/faq_show.php?q_id=393
4. Execute "/var/packages/MailServer/target/sbin/postsuper -d ALL" to delete all queued(stuck) mails.
This will also delete the non-spam mails which stuck in the queue.
2. Check every account, if the password is too simple to guess (ex: account and password is the same or the password is the continuous number like 1234), please change it.
We also provide firewall and autoblock to strength the security and we will suggest to use strong password for your DS accounts when DS is assessable to WAN at WebUI > Control Panel > User > Password Strength
3. If user doesn't enable auto-block or "Sender name and login name must be identical", please enable it.
Enable auto-block can block those who want to hack your ds, enable "Sender name and login name must be identical" can help to trace the hacked account.
4. The mail server had send a lot of spam mail, it might be add to the spam list.
Contact to ISP and change the IP, or others mail servers which blocked you it might unable to send mails to a lot of mail servers.
5. After clean stuck mails and password check, Now user can enable the smtp or mail server.
6. If you install the 3rd-party software like ipkg, SabNZB, Python, Twonky, OPT, we will first suggest that you make a reset by this way to get a fresh system:
http://www.synology.com/support/tutorials_show.php?q_id=493&
http://www.synology.com/support/faq_show.php?q_id=348&
We do not officially support 3rd-party software and it is violating the warranty policy. We don't officially supported it, so we are unable to ensure its compatibility with the DS and DSM update, not to say it is likely to cause DS to behave abnormally.
Otherwise if you have any spare disk, please try to install the clean system on the spare disk, and let the issue happen once and send us the new log.
If problem still persist after re-install the clean DSM system, please feel free to contact Synology support again.